New Paradigm of Biomolecular Soft-interfaces as Chiral Reaction Fields for Supramolecular Asymmetric Photochirogenesis
نویسندگان
چکیده
منابع مشابه
Mammalian serum albumins as a chiral mediator library for bio-supramolecular photochirogenesis: optimizing enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylate.
A simple strategy for choosing optimal bio-supramolecular mediators from the mammalian serum albumin library is proposed for bimolecular photochirogenic reactions. Thus, the enantiodifferentiating photocyclodimerization of 2-anthracencecarboxylate (AC) was optimized in chemical and optical yields, when mediated by porcine and canine serum albumins, both of which bound two AC molecules in the fi...
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ژورنال
عنوان ژورنال: Hyomen Kagaku
سال: 2012
ISSN: 0388-5321,1881-4743
DOI: 10.1380/jsssj.33.27